To send an e-mail message (entering the address automatically from the address book)
On the toolbar of Outlook Express, click the New Mail button.
To enter an e-mail name from the Address Book, click the book icon in the New Message window next to To:,
and then Double-click a name in the, err, Name column..
The addresee appears in the Message recipients: window
The addresee appears in the To: field of the New Message window, and that's it! You can start typing your message, as normal.
After typing your message, click the Send button on the New Message toolbar.